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Accessibility information
Author(s):   Burr, J.G.; Strong, J.D.
Title:   A nonchain process for formation of methane and toluene in the pyrolytic hydrogenolysis of xylenes
Journal:   J. Am. Chem. Soc.
Volume:   86
Page(s):  
Year:   1964
Reference type:   Journal article
Squib:   1964BUR/STR5065

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1964BUR/STR5065   1,2-Dimethylbenzene → Products  917 - 978   1.19E07       2.64E05      1
  1964BUR/STR5065   1,2-Dimethylbenzene + ·CH3CH4 + 2-Methylbenzyl  955 - 980   5.30              2
  Reference reaction:  H2 + ·CH3CH4 + 2
  1964BUR/STR5065   1,2-Dimethylbenzene + Phenyl, 2-methyl- → Toluene + 2-Methylbenzyl  955 - 980   10.70              2
  Reference reaction:  H2 + Phenyl, 2-methyl- → Toluene + 2
  1964BUR/STR5065   1,4-Dimethylbenzene → Products  949 - 1030   3.79E07       2.84E05      1
  1964BUR/STR5065   1,4-Dimethylbenzene + ·CH3CH4 + 4-Methylbenzyl  955 - 979   5.30              2
  Reference reaction:  H2 + ·CH3CH4 + 2
  1964BUR/STR5065   1,4-Dimethylbenzene + Phenyl, 4-methyl- → Toluene + 4-Methylbenzyl  955 - 979   10.70              2
  Reference reaction:  H2 + Phenyl, 4-methyl- → Toluene + 2
  1964BUR/STR5065   1,3-Dimethylbenzene → Products  922 - 979   8.73E06       2.71E05      1
  1964BUR/STR5065   1,3-Dimethylbenzene + ·CH3CH4 + 3-Methylbenzyl  955 - 982   5.30              2
  Reference reaction:  H2 + ·CH3CH4 + 2
  1964BUR/STR5065   1,3-Dimethylbenzene + Phenyl, 3-methyl- → Toluene + 3-Methylbenzyl  955 - 982   10.70              2
  Reference reaction:  H2 + Phenyl, 3-methyl- → Toluene + 2
  1964BUR/STR5065   Benzene, 1,2-di(methyl-d3)- → Products  980   9.91E08              1
  1964BUR/STR5065   Benzene, 1,4-di(methyl-d3)- → Products  979   3.64E08              1
  1964BUR/STR5065   Benzene, 1,3-di(methyl-d3)- → Products  982   8.24E08              1

Search returned 12 records.