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Title: Correlation of activation energies and bond energies in CF3 reactions
Journal: J. Chem. Phys.
Volume: 41
Page(s):
Year: 1964
Reference type: Journal article
Squib: 1964CAR/JOH1975
Reaction:
CHCl3 + ·CF3 → CHF3 + ·CCl3
Reaction order:
2
Temperature:
450 - 550
K
Rate expression:
2.01x10-11 [cm3/molecule s] e-29683 [J/mole]/RT
Category: Theory
Data type:
Bond energy-bond order (BEBO)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 450 | 7.20E-15 |
| 475 | 1.09E-14 |
| 500 | 1.59E-14 |
| 525 | 2.24E-14 |
| 550 | 3.05E-14 |