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Accessibility information
Author(s):   Carmichael, H.; Johnston, H.S.
Title:   Correlation of activation energies and bond energies in CF3 reactions
Journal:   J. Chem. Phys.
Volume:   41
Year:   1964
Reference type:   Journal article
Squib:   1964CAR/JOH1975

Reaction:   CH2Cl2 + ·CF3CHF3 + CHCl2
Reaction order:   2
Temperature:   450 - 550 K
Rate expression:   2.01x10-11 [cm3/molecule s] e-34339 [J/mole]/RT
Category:  Theory
Data type:   Bond energy-bond order (BEBO)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
450 2.08E-15
475 3.36E-15
500 5.20E-15
525 7.70E-15
550 1.10E-14