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Title: Photo-initiated reactions of thiols and olefins. I. The thiyl radical catalyzed isomerization of butene-2 and 1,2-ethylene-d2
Journal: Can. J. Chem.
Volume: 42
Page(s): 2239 - 2249
Year: 1964
Reference type: Journal article
Squib: 1964GRA/MIE2239-2249
Reaction:
1,3-Butadiene + CH3S· → Adduct
Reaction order:
2
Temperature:
298
K
Rate expression:
7.47x10-13 [cm3/molecule s]
Bath gas:
CH3S·
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
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