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Accessibility information
Author(s):   Kerr, J.A.; Lissi, E.A.; Trotman-Dickenson, A.F.
Title:   Competitive alkali-metal flame reactions. The reactions of sodium and potassium atoms with alkyl halides and acetyl chloride
Journal:   J. Chem. Soc.
Page(s):  
Year:   1964
Reference type:   Journal article
Squib:   1964KER/LIS1673

Reaction:   CH3Br + K·CH3 + KBr
Reaction order:   2
Reference reaction:   C2H5Cl + K·C2H5 + KCl
Reference reaction order:   2
Temperature:   503 - 589 K
Pressure:  8.00E-3 - 1.07E-2 bar
Rate expression:   5.2x10-1 e18375 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
503 4.21E1
525 3.50E1
550 2.89E1
575 2.43E1
589 2.22E1