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Author(s):   Lapidus, G.; Barton, D.; Yankwich, P.E.
Title:   Kinetics and stoichiometry of the gas-phase decomposition of oxalic acid
Journal:   J. Phys. Chem.
Volume:   68
Page(s):   1863 - 1865
Year:   1964
Reference type:   Journal article
Squib:   1964LAP/BAR1863-1865

Reaction order:   1
Temperature:   400 - 430 K
Pressure:  1.20E-3 bar
Rate expression:   7.94x1011 [s-1] e-125549 [±5022 J/mole]/RT
Uncertainty:   100.0
Bath gas:   HOOCCOOH
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
400 3.20E-5
425 2.95E-4
430 4.46E-4