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Accessibility information
Author(s):   Pearson, J.M.; Szwarc, M.
Title:   Activation energies and entropies of activation of CF3 radical addition. Part 1. Gas phase
Journal:   Trans. Faraday Soc.
Volume:   60
Page(s):   553 - 563
Year:   1964
Reference type:   Journal article
Squib:   1964PEA/SZW553-563

Reaction:   1,3-Butadiene + ·CF3 → Adduct
Reaction order:   2
Reference reaction:   (CH3)2CHCH(CH3)2 + ·CF3 → Other Products + CHF3
Reference reaction order:   2
Temperature:   338 - 448 K
Pressure:  0.93 bar
Rate expression:   2.8 e15797 [J/mole]/RT
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
338 7.73E2
350 6.38E2
375 4.44E2
400 3.24E2
425 2.45E2
448 1.95E2