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Accessibility information
Author(s):   Pritchard, G.O.; Foote, J.K.
Title:   The reactions of C2F5 and C3F7 radicals with hydrogen and deuterium
Journal:   J. Phys. Chem.
Volume:   68
Page(s):  
Year:   1964
Reference type:   Journal article
Squib:   1964PRI/FOO1016

Reaction:   Propanal, pentafluoro- + C2F5C2F5H + Propyl,2,2,3,3,3-pentafluoro-1-oxo-
Reaction order:   2
Reference reaction:   C2F5 + D2D + Ethane-d, pentafluoro-
Reference reaction order:   2
Temperature:   419 - 586 K
Pressure:  1.87E-2 - 0.27 bar
Rate expression:   1.55x10-2±9.3x10-4 e33092 [±8314472 J/mole]/RT
Bath gas:   Propanal, pentafluoro-
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
419 2.07E2
425 1.81E2
450 1.08E2
475 6.75E1
500 4.44E1
525 3.04E1
550 2.15E1
575 1.57E1
586 1.38E1