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Accessibility information
Author(s):   Alcock, W.G.; Whittle, E.
Title:   Reactions of trifluoromethyl radicals with organic halides. Part I - Methyl halides
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   61
Page(s):  
Year:   1965
Reference type:   Journal article
Squib:   1965ALC/WHI244

Reaction:   CH3Br + ·CF3CHF3 + ·CH2Br
Reaction order:   2
Reference reaction:   CH3Br + ·CF3CF3Br + ·CH3
Reference reaction order:   2
Temperature:   417 - 673 K
Pressure:  4.53E-2 - 0.34 bar
Rate expression:   1.7x101±3.1 e-7317 [±8314472 J/mole]/RT
Bath gas:   CH3Br
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
417 2.06E0
425 2.14E0
450 2.41E0
475 2.67E0
500 2.92E0
525 3.18E0
550 3.43E0
575 3.68E0
600 3.92E0
625 4.16E0
650 4.39E0
673 4.60E0