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Title: 934. Reactions of difluoroamino-radicals. Part I. Hydrogen abstraction from acetone and the strength of the C-H bond in acetone
Journal: J. Chem. Soc.
Page(s): 5080 - 5082
Year: 1965
Reference type: Journal article
Squib: 1965GRZ/KER5080-5082
Reaction:
(CH3)2CO + NF2 → CH3C(O)CH2(·) + HNF2
Reaction order:
2
Temperature:
451 - 553
K
Pressure: 2.67E-3 bar
Rate expression:
8.52x10-14 [cm3/molecule s] e-81814 [±818 J/mole]/RT
Uncertainty:
1.12
Bath gas:
(CH3)2CO
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 451 | 2.85E-23 |
| 475 | 8.58E-23 |
| 500 | 2.42E-22 |
| 525 | 6.17E-22 |
| 550 | 1.45E-21 |
| 553 | 1.59E-21 |