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Accessibility information
Author(s):   Hunt, M.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   933. Pyrolyses of ethyl cyanide, t-butyl cyanide, cumyl cyanide, and acetamide, and bond strengths in cyanides
Journal:   J. Chem. Soc.
Page(s):   5074 - 5080
Year:   1965
Reference type:   Journal article
Squib:   1965HUN/KER5074-5080

Reaction:   C2H5CNCH2CHCN + H2
Reaction order:   1
Temperature:   959 - 1040 K
Pressure:  8.00E-3 - 2.13E-2 bar
Rate expression:   2.51x1012 [s-1] e-270220 [J/mole]/RT
Bath gas:   C2H5CN
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
959 4.80E-3
975 8.38E-3
1000 1.93E-2
1025 4.26E-2
1040 6.73E-2