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Title: Pyrolysis studies. XV. Thermal retrogade aldol condensation of β-hydroxy ketones
Journal: J. Org. Chem.
Volume: 30
Page(s): 2067 - 2068
Year: 1965
Reference type: Journal article
Squib: 1965SMI/YAT2067-2068
Reaction:
(CH3)2C(OH)CH2C(O)CH3 → (CH3)2CO + (CH3)2CO
Reaction order:
1
Temperature:
495 - 528
K
Rate expression:
3.27x1011 [s-1] e-135526 [J/mole]/RT
Bath gas:
(CH3)2C(OH)CH2C(O)CH3
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 495 | 1.64E-3 |
| 500 | 2.27E-3 |
| 525 | 1.07E-2 |
| 528 | 1.28E-2 |