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Accessibility information
Author(s):   Tsang, W.
Title:   Decyclization of cyclohexene, 4-methylcyclohexene, and 4-vinylcyclohexene in a single-pulse shock tube
Journal:   J. Chem. Phys.
Volume:   42
Page(s):   1805 - 1809
Year:   1965
Reference type:   Journal article
Squib:   1965TSA1805-1809

Reaction:   4-Vinylcyclohexene1,3-Butadiene + 1,3-Butadiene
Reaction order:   1
Temperature:   900 - 1050 K
Pressure:  0.53 - 1.63 bar
Rate expression:   1.58x1015 [s-1] e-259412 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
900 1.39E0
925 3.55E0
950 8.62E0
975 2.00E1
1000 4.45E1
1025 9.53E1
1050 1.97E2