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Accessibility information
Author(s):   Tsang, W.
Title:   Decyclization of cyclohexene, 4-methylcyclohexene, and 4-vinylcyclohexene in a single-pulse shock tube
Journal:   J. Chem. Phys.
Volume:   42
Page(s):   1805 - 1809
Year:   1965
Reference type:   Journal article
Squib:   1965TSA1805-1809

Reaction:   Cyclohexene, 4-methyl-1,3-Butadiene + CH3CH=CH2
Reaction order:   1
Temperature:   900 - 1150 K
Pressure:  0.53 - 1.63 bar
Rate expression:   1.35x1015 [s-1] e-278535 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
900 9.22E-2
925 2.52E-1
950 6.54E-1
975 1.62E0
1000 3.81E0
1025 8.64E0
1050 1.88E1
1075 3.95E1
1100 8.02E1
1125 1.58E2
1150 3.01E2