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Accessibility information
Author(s):   Tschuilow-Roux, E.
Title:   Kinetics of the thermal decomposition of C2F6 in the presence of H2 at 1300°-1600°K
Journal:   J. Chem. Phys.
Volume:   43
Page(s):   2251 - 2256
Year:   1965
Reference type:   Journal article
Squib:   1965TSC2251-2256

Reaction:   C2F6·CF3 + ·CF3
Reaction order:   1
Temperature:   1300 - 1600 K
Pressure:  4.03 - 4.49 bar
Rate expression:   4.3x1017 [s-1] e-394937 [±15797 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 5.82E1
1325 1.16E2
1350 2.25E2
1375 4.27E2
1400 7.92E2
1425 1.44E3
1450 2.55E3
1475 4.44E3
1500 7.60E3
1525 1.28E4
1550 2.11E4
1575 3.43E4
1600 5.50E4