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Accessibility information
Author(s):   Alcock, W.G.; Whittle, E.
Title:   Reactions of trifluoromethyl radicals with organic halies. Part 3.-Chloromethanes, using hexafluoroacetone as a source of radicals
Journal:   Trans. Faraday Soc.
Volume:   62
Page(s):  
Year:   1966
Reference type:   Journal article
Squib:   1966ALC/WHI134

Reaction:   CHCl3 + ·CF3CHF3 + ·CCl3
Reaction order:   2
Reference reaction:   CHCl3 + ·CF3CF3Cl + CHCl2
Reference reaction order:   2
Temperature:   367 - 569 K
Pressure:  6.40E-2 bar
Rate expression:   1.03x10-1±1.6x10-2 e22200 [±8314472 J/mole]/RT
Bath gas:   CHCl3
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
367 1.49E2
375 1.27E2
400 8.16E1
425 5.51E1
450 3.89E1
475 2.84E1
500 2.15E1
525 1.67E1
550 1.32E1
569 1.12E1