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Title: The role of sulfur hexafluoride in the pyrolysis of Di-t-butyl peroxide: Chemical sensitization of the reaction of methyl radicals with sulfur hexafluoride
Journal: J. Phys. Chem.
Volume: 70
Page(s):
Year: 1966
Reference type: Journal article
Squib: 1966BAT/CRU723
Reaction:
·CH3 + SF6 → CH3F + SF5
Reaction order:
2
Temperature:
413 - 443
K
Pressure: 6.67E-2 - 0.33 bar
Rate expression:
3.32x10-11 [cm3/molecule s] e-59033 [J/mole]/RT
Bath gas:
(tert-C4H9O)2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 413 | 1.14E-18 |
| 425 | 1.85E-18 |
| 443 | 3.64E-18 |