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Author(s):   Batt, L.; Cruickshank, F.R.
Title:   The role of sulfur hexafluoride in the pyrolysis of Di-t-butyl peroxide: Chemical sensitization of the reaction of methyl radicals with sulfur hexafluoride
Journal:   J. Phys. Chem.
Volume:   70
Year:   1966
Reference type:   Journal article
Squib:   1966BAT/CRU723

Reaction:   ·CH3 + SF6CH3F + SF5
Reaction order:   2
Temperature:   413 - 443 K
Pressure:  6.67E-2 - 0.33 bar
Rate expression:   3.32x10-11 [cm3/molecule s] e-59033 [J/mole]/RT
Bath gas:   (tert-C4H9O)2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
413 1.14E-18
425 1.85E-18
443 3.64E-18