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Accessibility information
Author(s):   Callear, A.B.; Tyerman, W.J.R.
Title:   Rate parameters for reaction of atomic selenium with olefins
Journal:   Trans. Faraday Soc.
Volume:   62
Page(s):   2760 - 2767
Year:   1966
Reference type:   Journal article
Squib:   1966CAL/TYE2760-2767

Reaction:   CH2CHCN + Se → Adduct
Reaction order:   2
Reference reaction:   C2H4 + Se → Selenirane
Reference reaction order:   2
Temperature:   302 - 418 K
Pressure:  6.67E-2 bar
Rate expression:   1.08x10-1 e9146 [±8314472 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
302 4.12E0
325 3.19E0
350 2.50E0
375 2.03E0
400 1.69E0
418 1.50E0