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Author(s):   Carlton, T.S.; Steeper, J.R.; Christensen, R.L.
Title:   Rates of hydrogen abstraction from methanol by CF3 radicals
Journal:   J. Phys. Chem.
Volume:   70
Year:   1966
Reference type:   Journal article
Squib:   1966CAR/STE3222

Reaction:   CH3OH + ·CF3CHF3 + CH3
Reaction order:   2
Reference reaction:   CD3OD + ·CF3 → Other Products + CDF3
Temperature:   407 - 525 K
Pressure:  1.12E-2 - 9.55E-2 bar
Rate expression:   2.51x10-13 [cm3/molecule s] e-34754 [±3816 J/mole]/RT
Bath gas:   (CF3N)2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
407 8.69E-18
425 1.34E-17
450 2.32E-17
475 3.78E-17
500 5.87E-17
525 8.74E-17