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Title: Theoretical treatment of the pressure dependence of the unimolecular rate constant. Part 1. Cyclobutene, 1-methylcyclobutene and 3-methylcyclobutene
Journal: Trans. Faraday Soc.
Volume: 62
Page(s): 895 - 909
Year: 1966
Reference type: Journal article
Squib: 1966ELL/FRE895-909
Reaction:
Cyclobutene → 1,3-Butadiene
Reaction order:
1
Temperature:
415 - 430
K
Rate expression:
1.22x1013 [s-1] e-135526 [J/mole]/RT
Bath gas:
1,3-Butadiene
Category: Experiment
Data type:
RRK(M) extrapolation
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 415 | 1.07E-4 |
| 425 | 2.69E-4 |
| 430 | 4.20E-4 |