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Author(s):   Greig, G.; Thynne, J.C.J.
Title:   Hydrogen and deuterium atom abstraction from trideuteromethyl mercaptan by methyl radicals. Reactivity of methylthio radicals
Journal:   Trans. Faraday Soc.
Volume:   62
Page(s):
Year:   1966
Reference type:   Journal article
Squib:   1966GRE/THY379

Associated entries:

Search Results

Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
1966GRE/THY379	(CH₃)2CO + ·CH₃ → CH₄ + CH₃C(O)CH₂(·)	398 - 473	3.72E-13	3.99E04	2
1966GRE/THY379	(CD₃)2CO + CD₃ → ·CD₂C(O)CD₃ + CD₄	398 - 473	6.18E-13	4.73E04	2
1966GRE/THY379	CD₃ + CD₂HC(O)CD₃ → ·CD₂C(O)CD₃ + CHD₃	398 - 473	1.23E-14	3.97E04	2
1966GRE/THY379	·CH₃ + CD₃SH → ·CD₂SH + CH₃D	398 - 473	1.26E-13	3.46E04	2
1966GRE/THY379	·CH₃ + CD₃SH → CH₄ + CD₃S	398 - 473	1.78E-13	1.71E04	2
1966GRE/THY379	·CH₃ + CD₃SH → CH₃SH + CD₃	398 - 473	8.92E-14	3.18E04	2

Search returned 6 records.