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Accessibility information
Author(s):   Halstead, C.J.; Thrush, B.A.
Title:   The kinetics of elementary reactions involving the oxides of sulphur. III. The chemiluminescent reaction between sulphur monoxide and ozone
Journal:   Proc. R. Soc. London A
Volume:   295
Page(s):   380 - 398
Year:   1966
Reference type:   Journal article
Squib:   1966HAL/THR380-398

Reaction:   O3 + SOSO2 + O2
Reaction order:   2
Temperature:   223 - 300 K
Pressure:  4.00E-4 - 4.00E-3 bar
Rate expression:   4.15x10-12 [±3.32x10-13 cm3/molecule s] e-8813 [±8314472 J/mole]/RT
Bath gas:   SO
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Chemiluminescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
223 3.58E-14
225 3.73E-14
250 5.98E-14
275 8.79E-14
300 1.21E-13