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Accessibility information
Author(s):   Olschewski, H.A.; Troe, J.; Wagner, H.Gg.
Title:   Untersuchung unimolekularer Reaktionen bei hohen Drucken in Stosswellen: Zerfall von CS2 und CO2
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   70
Page(s):   1060 - 1064
Year:   1966
Reference type:   Journal article
Squib:   1966OLS/TRO1060-1064

Reaction:   CO2CO +
Reaction order:   1
Temperature:   2800 - 3700 K
Pressure:  12.16 - 24.26 bar
Rate expression:   2.51x1011 [s-1] e-460622 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Other (IR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
2800 6.41E2
2850 9.07E2
2900 1.27E3
2950 1.75E3
3000 2.40E3
3050 3.24E3
3100 4.35E3
3150 5.78E3
3200 7.60E3
3250 9.92E3
3300 1.28E4
3350 1.65E4
3400 2.10E4
3450 2.67E4
3500 3.35E4
3550 4.19E4
3600 5.20E4
3650 6.43E4
3700 7.89E4