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Accessibility information
Author(s):   Shaw, R.; Thynne, J.C.J.
Title:   Hydrogen and deuterium atom abstraction from methanol and trideuteromethanol. Reaction of methoxy radicals with methane
Journal:   Trans. Faraday Soc.
Volume:   62
Year:   1966
Reference type:   Journal article
Squib:   1966SHA/THY104

Reaction:   CH3OH + CD3 → Other Products + CHD3
Reaction order:   2
Reference reaction:   CD3 + CD3C2D6
Temperature:   398 - 523 K
Pressure:  4.00E-2 - 8.00E-2 bar
Rate expression:   7.95x10-14 [cm3/molecule s] e-35170 [±352 J/mole]/RT
Bath gas:   (CD3)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
398 1.93E-18
400 2.03E-18
425 3.79E-18
450 6.58E-18
475 1.08E-17
500 1.68E-17
523 2.44E-17