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Title: Hydrogen and deuterium atom abstraction from methanol and trideuteromethanol. Reaction of methoxy radicals with methane
Journal: Trans. Faraday Soc.
Volume: 62
Page(s):
Year: 1966
Reference type: Journal article
Squib: 1966SHA/THY104
Reaction:
CH4 + CH3O· → CH3OH + ·CH3
Reaction order:
2
Temperature:
403 - 523
K
Pressure: 4.00E-2 - 8.00E-2 bar
Rate expression:
1.05x10-12 [cm3/molecule s] e-46062 [J/mole]/RT
Bath gas:
(CD3)2CO
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 403 | 1.12E-18 |
| 425 | 2.29E-18 |
| 450 | 4.72E-18 |
| 475 | 9.02E-18 |
| 500 | 1.62E-17 |
| 523 | 2.63E-17 |