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Accessibility information
Author(s):   Tedder, J.M.; Watson, R.A.
Title:   Free radical substitution in aliphatic compounds. Part 11.-Reaction of trichloromethyl radicals with n-butane
Journal:   Trans. Faraday Soc.
Volume:   62
Year:   1966
Reference type:   Journal article
Squib:   1966TED/WAT1215

Reaction:   n-C4H10 + ·CCl3 → Other Products + CHCl3
Reaction order:   2
Reference reaction:   ·CCl3 + ·CCl3CCl3CCl3
Temperature:   419 - 530 K
Pressure:  0.13 - 0.13 bar
Rate expression:   1.26x10-14 [cm3/molecule s] e-31512 [J/mole]/RT
Bath gas:   n-C4H10
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
419 1.49E-18
425 1.69E-18
450 2.78E-18
475 4.32E-18
500 6.44E-18
525 9.24E-18
530 9.90E-18