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Author(s):   Walsh, R.; Golden, D.M.; Benson, S.W.
Title:   The thermochemistry of the gas phase equilibrium I2 + C6H5CH3 = C6H5CH2I + HI and the heat of formation of the benzyl radical
Journal:   J. Am. Chem. Soc.
Volume:   88
Page(s):   650 - 656
Year:   1966
Reference type:   Journal article
Squib:   1966WAL/GOL650-656

Reaction:   Toluene + I → Benzyl + HI
Reaction order:   2
Temperature:   490 - 510 K
Pressure:  3.60E-2 - 0.40 bar
Rate expression:   9.33x10-13 [cm3/molecule s] e-63606 [±4448 J/mole]/RT
Uncertainty:   3.1600001
Bath gas:   Toluene
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
490 1.55E-19
500 2.11E-19
510 2.85E-19