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Author(s):   Benson, S.W.; Shaw, R.
Title:   Kinetics and mechanism of the pyrolysis of 1,3-cyclohexadiene. A thermal source of cyclohexadienyl radicals and hydrogen atoms. The addition of hydrogen atoms to benzene and toluene
Journal:   J. Am. Chem. Soc.
Volume:   89
Year:   1967
Reference type:   Journal article
Squib:   1967BEN/SHA5351

Reaction:   Toluene + → Cyclohexadienyl, 6-methyl-
Reaction order:   2
Reference reaction:   Benzene + → Cyclohexadienyl
Reference reaction order:   2
Temperature:   664 K
Pressure:  1.33E-2 - 0.12 bar
Rate expression:   1.5
Bath gas:   1,3-Cyclohexadiene
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

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