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Accessibility information
Author(s):   Benson, S.W.; Spokes, G.N.
Title:   Application of very low pressure pyrolysis to combustion kinetics
Journal:   Symp. Int. Combust. Proc.
Volume:   11
Page(s):   95 - 103
Year:   1967
Reference type:   Journal article
Squib:   1967BEN/SPO95-103

Reaction:   CH3CCl3CH2=CCl2 + HCl
Reaction order:   1
Temperature:   900 - 1250 K
Rate expression:   6.3x1013 [s-1] e-216176 [J/mole]/RT
Bath gas:   CH3CCl3
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
900 1.79E1
925 3.91E1
950 8.19E1
975 1.65E2
1000 3.22E2
1025 6.07E2
1050 1.11E3
1075 1.97E3
1100 3.42E3
1125 5.79E3
1150 9.56E3
1175 1.55E4
1200 2.45E4
1225 3.82E4
1250 5.83E4