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Title: Application of very low pressure pyrolysis to combustion kinetics
Journal: Symp. Int. Combust. Proc.
Volume: 11
Page(s): 95 - 103
Year: 1967
Reference type: Journal article
Squib: 1967BEN/SPO95-103
Reaction:
CH3CCl3 → CH2=CCl2 + HCl
Reaction order:
1
Temperature:
900 - 1250
K
Rate expression:
6.3x1013 [s-1] e-216176 [J/mole]/RT
Bath gas:
CH3CCl3
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 900 | 1.79E1 |
| 925 | 3.91E1 |
| 950 | 8.19E1 |
| 975 | 1.65E2 |
| 1000 | 3.22E2 |
| 1025 | 6.07E2 |
| 1050 | 1.11E3 |
| 1075 | 1.97E3 |
| 1100 | 3.42E3 |
| 1125 | 5.79E3 |
| 1150 | 9.56E3 |
| 1175 | 1.55E4 |
| 1200 | 2.45E4 |
| 1225 | 3.82E4 |
| 1250 | 5.83E4 |