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Title: Hydrogen abstraction from chlorinated ethanes by chlorine atoms
Journal: Trans. Faraday Soc.
Volume: 63
Page(s): 1631 - 1635
Year: 1967
Reference type: Journal article
Squib: 1967CIL/GOL1631-1635
Reaction:
CH3CCl3 + Cl → HCl + CCl3CH2
Reaction order:
2
Reference reaction:
CH3Cl + Cl → ·CH2Cl + HCl
Temperature:
323 - 423
K
Pressure: 0.20 - 2.72 bar
Rate expression:
4.17x10-12 [cm3/molecule s] e-15049 [J/mole]/RT
Bath gas:
H2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 323 | 1.54E-14 |
| 325 | 1.59E-14 |
| 350 | 2.37E-14 |
| 375 | 3.34E-14 |
| 400 | 4.52E-14 |
| 423 | 5.78E-14 |