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Accessibility information
Author(s):   East, R.L.; Phillips, L.
Title:   Pressure-dependence of the gas-phase pyrolysis of the s-butoxyl radical at 150-190°
Journal:   J. Chem. Soc. A
Page(s):  
Year:   1967
Reference type:   Journal article
Squib:   1967EAS/PHI1939

Reaction:   2-C4H9O + NOC2H5COCH3 + HNO
Reaction order:   2
Reference reaction:   2-C4H9O → CH3CHO + ·C2H5
Reference reaction order:   2
Temperature:   423 - 463 K
Pressure:  1.60E-2 - 0.27 bar
Rate expression:   2.88x10-5 e44316 [J/mole]/RT
Bath gas:   sec-C4H9NO2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
423 8.54E0
425 8.05E0
450 4.01E0
463 2.88E0