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Accessibility information
Author(s):   Giles, R.D.; Quick, L.M.; Whittle, E.
Title:   Reactions of trifluoromethyl radicals with organic halides. Part 5.-Fluoromethanes and fluoroethanes
Journal:   Trans. Faraday Soc.
Volume:   63
Page(s):  
Year:   1967
Reference type:   Journal article
Squib:   1967GIL/QUI662

Reaction:   C2F5H + ·CF3CHF3 + C2F5
Reaction order:   2
Reference reaction:   CD4 + ·CF3 → CDF3 + CD3
Reference reaction order:   2
Temperature:   420 - 606 K
Rate expression:   1.03x10-1±2.0x10-2 e13386 [±803 J/mole]/RT
Bath gas:   (CF3)2CO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
420 4.76E0
425 4.55E0
450 3.69E0
475 3.05E0
500 2.58E0
525 2.21E0
550 1.92E0
575 1.69E0
600 1.51E0
606 1.47E0