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Accessibility information
Author(s):   Good, A.; Thynne, J.C.J.
Title:   Reaction of free radicals with sulphur dioxide. Part 1.-Methyl radicals
Journal:   Trans. Faraday Soc.
Volume:   63
Year:   1967
Reference type:   Journal article
Squib:   1967GOO/THY2708

Reaction:   CH3S(O)2 → ·CH3 + SO2
Reaction order:   1
Temperature:   298 - 437 K
Rate expression:   1.0x1013 [s-1] e-93954 [J/mole]/RT
Bath gas:   (CH3N)2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
298 3.40E-4
300 4.38E-4
325 7.94E-3
350 9.52E-2
375 8.19E-1
400 5.38E0
425 2.84E1
437 5.89E1