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Accessibility information
Author(s):   Olschewski, H.A.; Troe, J.; Wagner, H.GG.
Title:   Studies of unimolecular reactions of triatomic molecules
Journal:   Symp. Int. Combust. Proc.
Volume:   11
Page(s):  
Year:   1967
Reference type:   Journal article
Squib:   1967OLS/TRO155

Reaction:   CO2CO +
Reaction order:   1
Temperature:   2800 - 3500 K
Rate expression:   2.0x1011 [s-1] e-464779 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   IR absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
2800 4.27E2
2850 6.06E2
2900 8.50E2
2950 1.18E3
3000 1.62E3
3050 2.19E3
3100 2.95E3
3150 3.93E3
3200 5.18E3
3250 6.78E3
3300 8.80E3
3350 1.13E4
3400 1.45E4
3450 1.84E4
3500 2.32E4