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Accessibility information
Author(s):   Quee, M.J.Y.; Thynne, J.C.J.
Title:   Pressure-dependence of decomposition of tert-butoxyl radical
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   63
Year:   1967
Reference type:   Journal article
Squib:   1967QUE/THY2970

Reaction:   (CH3)3CO· → (CH3)2CO + ·CH3
Reaction order:   1
Reference reaction:   (CH3)3CO· + NO(CH3)3CONO
Temperature:   398 - 436 K
Pressure:  1.01E-2 - 4.53E-2 bar
Rate expression:   5.01x1014 [s-1] e-95616 [J/mole]/RT
Bath gas:   (tert-C4H9O)2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
398 1.42E2
400 1.64E2
425 8.88E2
436 1.76E3