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Title: Pressure-dependence of decomposition of tert-butoxyl radical
Journal: J. Chem. Soc. Faraday Trans.
Volume: 63
Page(s):
Year: 1967
Reference type: Journal article
Squib: 1967QUE/THY2970
Reaction:
(CH3)3CO → (CH3)2CO + ·CH3
Reaction order:
2
Reference reaction:
(CH3)3CO + NO → (CH3)3CONO
Temperature:
398 - 436
K
Pressure: 1.01E-2 - 4.53E-2 bar
Rate expression:
8.32x10-9 [cm3/molecule s] e-56040 [J/mole]/RT
Bath gas:
(tert-C4H9O)2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 398 | 3.68E-16 |
| 400 | 4.00E-16 |
| 425 | 1.08E-15 |
| 436 | 1.61E-15 |