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Accessibility information
Author(s):   Amphlett, J.C.; Whittle, E.
Title:   Bromination of fluoroalkanes. Part 4.-Kinetics of thermal bromination of fluoroform and pentafluorethane
Journal:   Trans. Faraday Soc.
Volume:   64
Page(s):  
Year:   1968
Reference type:   Journal article
Squib:   1968AMP/WHI2130

Reaction:   n-C4H10 + Br·sec-C4H9 + HBr
Reaction order:   2
Temperature:   423 - 483 K
Rate expression:   4.78x10-10 [cm3/molecule s] e-43900 [±881 J/mole]/RT
Uncertainty:   1.21
Bath gas:   n-C4H10
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
423 1.81E-15
425 1.92E-15
450 3.84E-15
475 7.11E-15
483 8.55E-15