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Accessibility information
Author(s):   Gray, P.; Herod, A.A.
Title:   Methyl radical reactions with ethanol and deuterated ethanols
Journal:   Trans. Faraday Soc.
Volume:   64
Page(s):  
Year:   1968
Reference type:   Journal article
Squib:   1968GRA/HER1568

Reaction:   C2H5OH + ·CH3CH4 + CH3CH2
Reaction order:   2
Reference reaction:   ·CH3 + ·CH3C2H6
Temperature:   403 - 523 K
Rate expression:   1.32x10-13 [cm3/molecule s] e-39327 [J/mole]/RT
Bath gas:   (CH3)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
403 1.05E-18
425 1.93E-18
450 3.59E-18
475 6.24E-18
500 1.03E-17
523 1.56E-17