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Accessibility information
Author(s):   Kerr, J.A.; Smith, B.J.A.; Trotman-Dickenson, A.F.; Young, J.C.
Title:   The abstraction of halogen atoms from alkyl halides by the trichlorosilyl radical
Journal:   J. Chem. Soc. A
Page(s):   510 - 513
Year:   1968
Reference type:   Journal article
Squib:   1968KER/SMI510-513

Reaction:   CH3Br + SiCl3·CH3 + Silane, bromotrichloro-
Reaction order:   2
Reference reaction:   CH3Cl + SiCl3·CH3 + SiCl4
Reference reaction order:   2
Temperature:   373 - 573 K
Rate expression:   2.7x10-1 e22532 [J/mole]/RT
Bath gas:   SiHCl3
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
373 3.86E2
375 3.71E2
400 2.36E2
425 1.59E2
450 1.11E2
475 8.11E1
500 6.10E1
525 4.71E1
550 3.73E1
573 3.06E1