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Accessibility information
Author(s):   Morris, E.R.; Thynne, J.C.J.
Title:   Reactions of radicals containing fluorine. Part 1.-Hydrogen and deuterium atom abstraction from trideuteromethanol by trifluoromethyl radicals
Journal:   Trans. Faraday Soc.
Volume:   64
Page(s):  
Year:   1968
Reference type:   Journal article
Squib:   1968MOR/THY414

Reaction:   CH3OH + ·CF3 → Other Products + CHF3
Reaction order:   2
Reference reaction:   ·CF3 + ·CF3C2F6
Temperature:   357 - 435 K
Pressure:  2.40E-2 - 4.40E-2 bar
Rate expression:   1.38x10-14 [cm3/molecule s] e-15631 [±1098 J/mole]/RT
Uncertainty:   1.41
Bath gas:   CF3I
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
357 7.13E-17
375 9.19E-17
400 1.26E-16
425 1.66E-16
435 1.83E-16