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Title: Free radical substitution in aliphatic compounds. Part 17.-Reaction of trichloromethyl radicals with 1-fluorobutane and 1,1,1 trifluoropentane
Journal: Trans. Faraday Soc.
Volume: 64
Page(s):
Year: 1968
Reference type: Journal article
Squib: 1968TED/WAT1304
Reaction:
Pentane, 1,1,1-trifluoro- + ·CCl3 → Other Products + CHCl3
Reaction order:
2
Reference reaction:
·CCl3 + ·CCl3 → CCl3CCl3
Temperature:
418 - 503
K
Pressure: 0.13 - 0.13 bar
Rate expression:
1.69x10-15 [cm3/molecule s] e-17045 [±681 J/mole]/RT
Uncertainty:
1.23
Bath gas:
Pentane, 1,1,1-trifluoro-
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 418 | 1.26E-17 |
| 425 | 1.36E-17 |
| 450 | 1.78E-17 |
| 475 | 2.26E-17 |
| 500 | 2.81E-17 |
| 503 | 2.88E-17 |