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Author(s):   Walker, R.F.; Phillips, L.
Title:   The kinetics of disproportionation-combination reactions between the s-butoxy-radical and nitric oxide, and of the pyrolysis of the O-O bond in di-s-butyl peroxide in the gas phase
Journal:   J. Chem. Soc. London A
Page(s):   2103 - 2106
Year:   1968
Reference type:   Journal article
Squib:   1968WAL/PHI2103-2106

Reaction:   NO + CH3CH2CH(CH3)O → C2H5COCH3 + HNO
Reaction order:   2
Reference reaction:   NO + CH3CH2CH(CH3)O → CH3CH2CH(CH3)ONO
Temperature:   373 - 413 K
Rate expression:   2.16x10-14 [cm3/molecule s]
Bath gas:   Peroxide, bis(1-methylpropyl)
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

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