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Title: The kinetics of disproportionation-combination reactions between the s-butoxy-radical and nitric oxide, and of the pyrolysis of the O-O bond in di-s-butyl peroxide in the gas phase
Journal: J. Chem. Soc. London A
Page(s): 2103 - 2106
Year: 1968
Reference type: Journal article
Squib: 1968WAL/PHI2103-2106
Reaction:
NO + CH3CH2CH(CH3)O → C2H5COCH3 + HNO
Reaction order:
2
Reference reaction:
NO + CH3CH2CH(CH3)O → CH3CH2CH(CH3)ONO
Reference reaction order:
2
Temperature:
373 - 413
K
Rate expression:
2.6x10-1±1.0x10-2
Bath gas:
Peroxide, bis(1-methylpropyl)
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
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