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Accessibility information
Author(s):   Yee Quee, M.J.; Thynne, J.C.J.
Title:   The pressure dependence of the decomposition of the isopropoxyl radical
Journal:   J. Phys. Chem.
Volume:   72
Page(s):  
Year:   1968
Reference type:   Journal article
Squib:   1968YEE/THY2824

Reaction:   i-C3H7O + (iso-C3H7O)2 → Other Products + iso-C3H7OH
Reaction order:   2
Reference reaction:   i-C3H7OCH3CHO + ·CH3
Reference reaction order:   2
Temperature:   395 - 428 K
Rate expression:   1.0x10-2 e-10892 [±8314472 J/mole]/RT
Uncertainty:   3.1600001
Bath gas:   (iso-C3H7O)2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
395 3.63E-4
400 3.78E-4
425 4.59E-4
428 4.69E-4