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Accessibility information
Author(s):   Cadman, P.; Tilsley, G.M.; Trotman-Dickenson, A.F.
Title:   Reactions of trichlorosilyl radicals with n-propyl chloride, cyclopentyl chloride, and carbon tetrachloride
Journal:   J. Chem. Soc. A
Page(s):   1370 - 1372
Year:   1969
Reference type:   Journal article
Squib:   1969CAD/TIL1370-1372

Reaction:   CCl4 + SiCl3·CCl3 + SiCl4
Reaction order:   2
Reference reaction:   CH3Cl + SiCl3·CH3 + SiCl4
Reference reaction order:   2
Temperature:   353 - 553 K
Rate expression:   1.15x101 e8398 [J/mole]/RT
Bath gas:   SiHCl3
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
353 2.01E2
375 1.70E2
400 1.44E2
425 1.24E2
450 1.09E2
475 9.64E1
500 8.67E1
525 7.87E1
550 7.21E1
553 7.14E1