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Title: Kinetic mechanisms in nitrogen-chlorine radical systems. Part 1 - The formation and detection of the NCl2 and N3 free radicals using time-resolved absorption spectrophotometry
Journal: J. Chem. Soc. Faraday Trans. 2
Volume: 65
Page(s):
Year: 1969
Reference type: Journal article
Squib: 1969CLA/CLY2994
Reaction:
Cl + NCl2 → Cl2 + NCl
Reaction order:
2
Temperature:
298
K
Pressure: 1.33E-3 - 4.00E-3 bar
Rate expression:
5.25x10-14 [cm3/molecule s]
Uncertainty:
1.78
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Vis-UV absorption
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