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Accessibility information
Author(s):   Clark, T.C.; Garnett, S.H.; Kistiakowsky, G.B.
Title:   Reaction of carbon dioxide with atomic oxygen and the dissociation of carbon dioxide in shock waves
Journal:   J. Chem. Phys.
Volume:   51
Page(s):  
Year:   1969
Reference type:   Journal article
Squib:   1969CLA/GAR2885

Reaction:   CO2CO +
Reaction order:   1
Temperature:   2900 - 4000 K
Pressure:  5.60E-2 bar
Rate expression:   5.13x107 [s-1] e-310130 [±27937 J/mole]/RT
Uncertainty:   2.29
Bath gas:   Ne
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
2900 1.33E2
3000 2.04E2
3100 3.05E2
3200 4.45E2
3300 6.33E2
3400 8.82E2
3500 1.21E3
3600 1.62E3
3700 2.15E3
3800 2.80E3
3900 3.60E3
4000 4.57E3