Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Emanuel, G.
Title:   Kinetics of complex molecules in aerodynamic flows
Journal:   Am. Inst. Aeronaut. Astronaut. (AIAA)
Volume:   7
Page(s):   1208 - 1209
Year:   1969
Reference type:   Journal article
Squib:   1969EMA1208-1209

Reaction:   SF6SF5 + ·F
Reaction order:   1
Temperature:   1000 - 4300 K
Pressure:  0.25 bar
Rate expression:   8.89x1012 [s-1] e-160469 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 3.69E4
1100 2.13E5
1200 9.20E5
1300 3.17E6
1400 9.16E6
1500 2.30E7
1600 5.13E7
1700 1.04E8
1800 1.96E8
1900 3.45E8
2000 5.73E8
2100 9.07E8
2200 1.38E9
2300 2.02E9
2400 2.86E9
2500 3.95E9
2600 5.31E9
2700 6.99E9
2800 9.02E9
2900 1.14E10
3000 1.43E10
3100 1.76E10
3200 2.14E10
3300 2.56E10
3400 3.05E10
3500 3.58E10
3600 4.17E10
3700 4.83E10
3800 5.54E10
3900 6.31E10
4000 7.14E10
4100 8.03E10
4200 8.98E10
4300 9.99E10