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Accessibility information
Author(s):   Franklin, J.A.; Huybrechts, G.; Cillien, C.
Title:   Addition of a chlorine atom to tetrachloroethylene
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   65
Page(s):   2094 - 2102
Year:   1969
Reference type:   Journal article
Squib:   1969FRA/HUY2094-2102

Reaction:   C2Cl5C2Cl4 + Cl
Reaction order:   1
Temperature:   310 - 348 K
Pressure:  0.19 - 0.86 bar
Rate expression:   3.24x1013 [s-1] e-67264 [J/mole]/RT
Bath gas:   H2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
310 1.50E2
325 5.01E2
348 2.60E3