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Title: Rates of reaction of atomic oxygen (O3P). Experimental method and results for some C1 to C5 chloroalkanes and bromoalkanes
Journal: J. Phys. Chem.
Volume: 73
Page(s): 1326 - 1335
Year: 1969
Reference type: Journal article
Squib: 1969HER/HUI1326-1335
Reaction:
CH3Br + O· → ·OH + ·CH2Br
Reaction order:
2
Temperature:
385 - 595
K
Pressure: 0.37 - 0.42 bar
Rate expression:
1.66x10-11 [cm3/molecule s] e-29101 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 385 | 1.87E-15 |
| 400 | 2.63E-15 |
| 425 | 4.40E-15 |
| 450 | 6.96E-15 |
| 475 | 1.05E-14 |
| 500 | 1.51E-14 |
| 525 | 2.11E-14 |
| 550 | 2.86E-14 |
| 575 | 3.77E-14 |
| 595 | 4.63E-14 |